Unveiling the TADF Emitters with Apparent Negative Singlet-Triplet Gaps: Implications for Exciton Harvesting and OLED Performance

Intramolecular through-space charge transfer thermally activated delayed fluorescence (TSCT-TADF) has attracted much attention recently as it can achieve both small energy splitting and high emission efficiency. However, the relationship of excited states between TSCT and through-bond charge transfer (TBCT) remains a challenge in the TSCT-TADF molecules. Herein, three compounds DPS-m-bAc, DPS-p-bAc, and DPS-OAc that possess […]