A Novel Carbazolophane: A Comparison of the Performance of Two Planar Chiral CP-TADF Emitters

Jasmin Seibert, Yan Xu, Hassan Hafeez, Joachim Podlech, Ludovic Favereau, Eduard Spuling, Charlotte Waldhelm, Martin Nieger, Olaf Fuhr, Zahid Hassan, Jeanne Crassous, Ifor D. W. Samuel, Eli Zysman-Colman, Stefan Bräse

The prototypical example of a (cyclo)phane, [2.2]paracyclophane (PCP), has proven to be a versatile stereogenic moiety within the design of circularly polarized thermally activated delayed fluorescence (CP-TADF) emitters; however, the exploration of other cyclophanes within CP-TADF emitter design has been largely neglected. Here, a comparative study of the photophysical and optoelectronic properties of two cyclophane […]